MATERIAL SAFETY DATA SHEET

 

1. CHEMICAL PRODUCT AND COMPANY INFORMATION

 

Product Name: SUNOCO FR

 

Manufacturer Information:

Sunoco, Inc. (R&M)

1735 Market Street LL

 

Philadelphia, Pennsylvania, 19103-7583

 

Product Use:

Racing fuel

 

Emergency Phone Numbers:

 

Chemtrec

(800) 424-9300

 

Sunoco Inc.

(800) 964-8861

 

 

Information:

 

Product Safety Information

(888) 567-3066

 

 

2. COMPOSITION/INFORMATION ON INGREDIENTS

 

Component

CAS No.

Amount (Vol%)

 

 

ALKYLATE

64741-66-8

50 - 60

 

TOLUENE

108-88-3

25 - 35

 

ETHYL ALCOHOL

64-17-5

10.2 - 10.2

 

N-BUTANE

106-97-8

9 - 9

 

N-HEXANE

110-54-3

1 - 2

 

XYLENE

1330-20-7

0.5 - 1.5

 

1,2,4-TRIMETHYLBENZENE

95-63-6

0.4 - 0.5

 

ETHYL BENZENE

100-41-4

0.1 - 0.2

 

BENZENE

71-43-2

0.1 - 0.15

 

CYCLOHEXANE

110-82-7

0.05 - 0.1

 

NAPHTHALENE

91-20-3

0.05 - 0.1

 

 

EXPOSURE GUIDELINES (SEE SECTION 15 FOR ADDITIONAL EXPOSURE LIMITS)

 

CAS No.

Governing Body

Exposure Limits

 

ALKYLATE

64741-66-8

Sunoco

TWA

100

ppm

BENZENE

71-43-2

ACGIH

STEL

2.5

ppm

BENZENE

71-43-2

OSHA

STEL

5

ppm

BENZENE

71-43-2

ACGIH

TWA

0.5

ppm

BENZENE

71-43-2

OSHA

TWA

1

ppm

CYCLOHEXANE

110-82-7

ACGIH

TWA

100

ppm

CYCLOHEXANE

110-82-7

OSHA

TWA

300

ppm

ETHYL ALCOHOL

64-17-5

ACGIH

TWA

1000

ppm

ETHYL ALCOHOL

64-17-5

OSHA

TWA

1000

ppm

ETHYL BENZENE

100-41-4

ACGIH

STEL

125

ppm

ETHYL BENZENE

100-41-4

ACGIH

TWA

100

ppm

ETHYL BENZENE

100-41-4

OSHA

TWA

100

ppm

N-BUTANE

106-97-8

ACGIH

TWA

1000

ppm

N-HEXANE

110-54-3

ACGIH

TWA

50

ppm

N-HEXANE

110-54-3

OSHA

TWA

500

ppm

NAPHTHALENE

91-20-3

ACGIH

STEL

15

ppm

NAPHTHALENE

91-20-3

ACGIH

TWA

10

ppm

NAPHTHALENE

91-20-3

OSHA

TWA

10

ppm

TOLUENE

108-88-3

NIOSH

STEL

150

ppm

TOLUENE

108-88-3

ACGIH

TWA

20

ppm

TOLUENE

108-88-3

OSHA

TWA

200

ppm

XYLENE

1330-20-7

ACGIH

STEL

150

ppm

XYLENE

1330-20-7

ACGIH

TWA

100

ppm

XYLENE

1330-20-7

OSHA

TWA

100

ppm

 

 

3. HAZARDS IDENTIFICATION

         EMERGENCY OVERVIEW

Danger! Extremely flammable liquid and vapor. Vapors may cause flash fire or explosion. Static accumulator. May form an ignitable vapor/air mixture. Excessive exposure to mists or vapors generated by heat may cause irritation to eyes, nose, throat, lungs and respiratory tract. Harmful or fatal if swallowed. Pulmonary aspiration hazard. While ingesting or vomiting, may enter lungs and produce damage. Harmful if inhaled. Overexposure may lead to serious disturbances of heart rhythm and nervous system effects, including drowsiness, dizziness, nausea, headaches, paralysis, loss of consciousness and even death. May cause skin irritation. May cause eye irritation. Contains material or materials that can cause birth defects. Contains material or materials that can cause cancer. May cause target organ or system damage to the following: eye, central nervous system, kidney, liver, respiratory system, skin, cardiovascular system, heart, peripheral nervous system, bone marrow,

 

Hazards Ratings:

Key: 0 = least, 1 = slight, 2 = moderate, 3 = high, 4 = extreme

 

Health

Fire

Reactivity

PPI

 

NFPA

1

3

0

 

HMIS

2

3

0

X

 

         POTENTIAL HEALTH EFFECTS

  PRE-EXISTING MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE

The following diseases or disorders may be aggravated by exposure to this product: skin, eye, blood forming organs, nervous system, respiratory system, lung (asthma-like conditions), cardiovascular system,

  INHALATION

High concentrations may lead to central nervous system effects (drowsiness, dizziness, nausea, headaches, paralysis and loss of consciousness and even death). May cause serious disturbances of heart rhythm. Excessive exposure to mists or vapors generated by heat may cause irritation to eyes, nose, throat, lungs and respiratory tract. Solvent "huffing/sniffing" (abuse) or intentional prolonged overexposure to high levels of vapors can produce abnormal behavior, convulsions, hallucinations, delerium, nervous system damage, serious disturbances of heart rhythm and sudden death. Repeated excessive exposures may cause blood disorders such as anemia and leukemia. Contains a material that has been related to cancer in humans.

 

 

LC50 (mg/l):

no data

 

 

LC50 (mg/m3):

no data

 

 

LC50 (ppm):

no data

 

 

  SKIN

Moderately irritating to the skin. Prolonged or repeated contact can result in defatting and drying of the skin which may result in skin irritation and dermatitis (rash).

 

 

Draize Skin Score:

no data

 

Out of 8.0

 

 

LD50 (mg/kg):

no data

 

 

  EYES

Moderately irritating to the eyes. Contact with the eye may cause redness, burning, tearing and/or blurred vision.

  INGESTION

Harmful or fatal if swallowed. Pulmonary aspiration hazard. While ingesting or vomiting, may enter lungs and produce damage. Irritating to mouth, throat, and stomach. Contains material or materials that can cause birth defects. May produce central nervous system effects, which includes dizziness, loss of balance and coordination, unconsciousness, coma and even death.

 

LD50 (g/kg):

no data

 

 

 

 

4. FIRST AID MEASURES

         INHALATION

Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen and continue to monitor. Get immediate medical attention.

         SKIN

Immediately flush with large amounts of water for 20 minutes, use soap if available. Remove contaminated clothing, including shoes, after flushing has begun. Get prompt medical attention. Injection injuries may not appear serious at first but within a few hours, without proper treatment, the area will become swollen, discolored and extremely painful. Wash clothing before reuse.

         EYES

Flush eye with water for 20 minutes. Get medical attention.

         INGESTION

If swallowed, immediately contact a physician or Poison Control Center. Never give anything by mouth to an intoxicated, unconscious or convulsing person. Get immediate medical attention. Do not induce vomiting!

 

 

5. FIRE FIGHTING MEASURES

         EXTINGUISHING MEDIA

The following media may be used to extinguish a fire involving this material: Alcohol resistant foam;

         FIRE FIGHTING INSTRUCTIONS

Use water spray to cool fire exposed tanks and containers. Wear structural fire fighting gear. The use of fresh air equipment such as Self Contained Breathing Apparatus (SCBA) or Supplied Air Respirators should be worn for fire fighting if exposure or potential exposure to products of combustion is expected.

         FLAMMABLE PROPERTIES

Flammable liquid and vapor. STATIC ACCUMULATOR. This liquid may form an ignitable vapor-air mixture in closed tanks or containers.

 

 

Typical

Minimum

Maximum

Text Result

Units

Method

 

Flash Point

 

 

 

Minus 40 est'd

F

N/A

 

Autoignition Temperature

 

 

 

536 estimated

F

N/A

Lower Explosion Limit

1.5

 

 

 

%

N/A

Upper Explosion Limit

7.6

 

 

 

%

N/A

 

 

6. ACCIDENTAL RELEASE MEASURES

Prevent ignition, stop leak and ventilate the area. Contain spilled liquid with sand or earth. DO NOT use combustible materials such as sawdust. Absorb spill with inert material (e.g., dry sand or earth), then place in a chemical waste container. Do not use spark-generating metals for sweeping up spilled material. Avoid runoff into storm sewers and ditches which lead to waterways. Vapor can be controlled using a water fog. Water streams should not be directed to the liquid as this will cause the liquid to boil and generate more vapor. Keep personnel upwind from leak. Use appropriate personal protective equipment as stated in Section 8 of this MSDS. Advise the Environmental Protection Agency (EPA) and appropriate state agencies, if required. Vacuum or sweep up material and place in a disposal container.

 

 

7. HANDLING AND STORAGE

         HANDLING

Follow all MSDS/label precautions even after container is emptied because it may retain product residue. STATIC ACCUMULATOR. This liquid may form an ignitable vapor-air mixture in closed tanks or containers. This liquid may accumulate static electricity even when transferred into properly grounded containers. Bonding and grounding may be insufficient to remove static electricity. Static electricity accumulation may be significantly increased by the presence of small quantities of water.Always bond receiving container to the fill pipe before and during loading, following NFPA-77 and/or API RP 2003 requirements. Automatic gauging devices and other floats in vessels or tanks which contain static accumulating liquids should be electrically bonded to the shell. Bonding and grounding alone may be inadequate to eliminate fire and explosion hazards associated with electrostatic charges. In addition to bonding and grounding, efforts to mitigate the hazards of an electrostatic discharge may include, but are not limited to, ventilation, inerting and/or reduction of transfer velocities. Always keep the nozzle in contact with the container throughout the loading process. Do not fill any portable containers in or on a vehicle. Special precautions, such as reduced loading rates and increased monitoring, must be observed during "switch loading" operations (i.e. loading this material in tanks or shipping compartments that previously contained middle distillates or similar products). Non-equilibrium conditions may increase the risks associated with static electricity such as tank and container filling, tank cleaning, sampling, gauging, loading, filtering, mixing, agitation, etc. Dissipation of electrostatic charges may be improved with the use of conductivity additives when used with other mitigating efforts, including bonding and grounding. Avoid breathing (dust, vapor, mist, gas). Use only in a well-ventilated area. Avoid contact with eyes, skin, and clothing. Wash thoroughly after handling. Never siphon by mouth. "Empty" containers retain product residue (liquid and/or vapor) and can be dangerous. DO NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. Empty drums should be completely drained, properly bunged, and promptly returned to a drum reconditioned, or properly disposed of.

         STORAGE

Keep away from heat, sparks, and flame. Keep container closed when not in use. Consult NFPA and / or OSHA codes for additional information. Store in a cool dry place. NFPA class IB storage. Flash point is less than 73 degrees F and boiling point is greater than or equal to 100 degrees F. Outside or detached storage is preferred.

 

 

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Consult With a Health and Safety Professional for Specific Selections

 

         ENGINEERING CONTROLS

Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits. Use with adequate ventilation. Local exhaust ventilation may be necessary to control any air contaminants to within their TLVs during the use of this product. Use explosion-proof ventilation equipment. Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower.

         PERSONAL PROTECTION

  EYE PROTECTION

Use chemical splash goggles and face shield (ANSI Z87.1 or approved equivalent).

  GLOVES or HAND PROTECTION

The glove(s) listed below may provide protection against permeation. Gloves of other chemically resistant materials may not provide adequate protection. Protective gloves are recommended to protect against contact with product. Nitrile; Viton; Teflon;

  RESPIRATORY PROTECTION

Concentration in air determines the level of respiratory protection needed. Use only NIOSH certified respiratory equipment. Half-mask air purifying respirator with organic vapor cartridges is acceptable for exposures to ten (10) times the exposure limit. Full-face air purifying respirator with organic vapor cartridges is acceptable for exposures to fifty (50) times the exposure limit. Exposure should not exceed the cartridge limit of 1000 ppm. Protection by air purifying respirators is limited. Use a positive pressure-demand full-face supplied air respirator or SCBA for exposures greater than fifty (50) times the exposure limit. If exposure is above the IDLH (Immediately Dangerous to Life and Health) or there is the possibility of an uncontrolled release, or exposure levels are unknown, then use a positive pressure-demand full-face supplied air respirator with escape bottle or SCBA. Wear a NIOSH-approved (or equivalent) full-facepiece airline respirator in the positive pressure mode with emergency escape provisions.

  OTHER

Where splashing is possible, full chemically resistant protective clothing and boots are required. The following materials are acceptable for use as protective clothing: Nitrile; Viton; Teflon; Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Remove contaminated clothing and wash before reuse. For non-fire emergencies, positive pressure SCBA and structural firefighter's protective clothing will provide only limited protection.

 

 

9. PHYSICAL AND CHEMICAL PROPERTIES

 

Physical Property

Typical

Units

Text Result

Reference

 

Appearance

 

N/A

Clear liquid

 

 

Boiling Point

 

F

100 - 430

 

 

Bulk Density

6.16

lb/gal

 

 

 

Liquid Conductivity

 

pS/m

< 50 (varies)

 

 

Melting Point

 

F

no data

 

 

Molecular Weight

 

g/mole

no data

 

 

Octanol/Water Coefficient

 

N/A

no data

 

 

pH

 

N/A

no data

 

 

Specific Gravity

0.74

N/A

 

 

 

Solubility In Water

 

wt %

Nil to 15%

 

 

Odor

 

N/A

Gasoline odor

 

 

Odor Threshold

 

ppm

< 1

 

 

Vapor Pressure

 

psia

5 - 16

 

 

Viscosity (F)

 

SUS

no data

 

 

Viscosity (C)

 

CsT

no data

 

 

% Volatile

100

wt %

 

 

 

 

 

10. STABILITY AND REACTIVITY

         STABILITY

Stable

         CONDITIONS TO AVOID

Avoid heat, sparks and open flame. Avoid static discharge

         INCOMPATIBILITY

Strong oxidizers Alkaline materials; Acids; Chlorine; Concentrated oxygen; Halogens and halogenated compounds; Hydrogen peroxide;

         HAZARDOUS DECOMPOSITION PRODUCTS

Combustion may produce carbon monoxide, carbon dioxide and other asphyxiants.

         HAZARDOUS POLYMERIZATION

Will not polymerize.

 

 

11. ECOLOGICAL INFORMATION

Gasoline spills are toxic to fish and aquatic flora.

 

 

12. DISPOSAL CONSIDERATIONS

Follow federal, state and local regulations. This material is a RCRA hazardous waste. Do not flush material to drain or storm sewer. Contract to authorized disposal service.

 

 

13. TRANSPORT INFORMATION

Governing Body

Mode

Proper Shipping Name

DOT

Ground

Gasohol

 

Governing Body

Mode

Hazard Class

UN/NA No.

Label

 

DOT

Ground

3 (Flammable liquid)

NA1203

 

 

 

14. REGULATORY INFORMATION

This product contains the following EPCRA section 313 chemicals subject to the reporting requirements of the Emergency Planning and Community Right-To-Know Act of 1986 (40 CFR 372): Maximum Wt%: Toulene- CAS Number 108-88-3, 41%; Xylene- CAS Number 1330-20-7. 1.7%; Ethyl benzene- CAS Number 100-41-4, 0.2%; N-Hexane- CAS Number 110-54-3, 4.5%; Naphthalene- CAS Number 91-20-3, 0.2%; Benzene- CAS Number 71-43-2, 0.2%. The remaining Sara 313 components listed in Section 14 of the MSDS are less than the reported de minimis levels. This information must be included in all MSDSs that are copied and distributed for this material.

Regulatory List

Component

CAS No.

 

ACGIH - Occupational Exposure Limits - Carcinogens

BENZENE

71-43-2

ACGIH - Occupational Exposure Limits - Carcinogens

ETHYL ALCOHOL

64-17-5

ACGIH - Occupational Exposure Limits - Carcinogens

ETHYL BENZENE

100-41-4

ACGIH - Occupational Exposure Limits - Carcinogens

NAPHTHALENE

91-20-3

ACGIH - Occupational Exposure Limits - Carcinogens

TOLUENE

108-88-3

ACGIH - Occupational Exposure Limits - Carcinogens

XYLENE

1330-20-7

ACGIH - Occupational Exposure Limits - TWAs

BENZENE

71-43-2

ACGIH - Occupational Exposure Limits - TWAs

CYCLOHEXANE

110-82-7

ACGIH - Occupational Exposure Limits - TWAs

ETHYL ALCOHOL

64-17-5

ACGIH - Occupational Exposure Limits - TWAs

ETHYL BENZENE

100-41-4

ACGIH - Occupational Exposure Limits - TWAs

N-BUTANE

106-97-8

ACGIH - Occupational Exposure Limits - TWAs

N-HEXANE

110-54-3

ACGIH - Occupational Exposure Limits - TWAs

NAPHTHALENE

91-20-3

ACGIH - Occupational Exposure Limits - TWAs

TOLUENE

108-88-3

ACGIH - Occupational Exposure Limits - TWAs

XYLENE

1330-20-7

ACGIH - Short Term Exposure Limits

BENZENE

71-43-2

ACGIH - Short Term Exposure Limits

ETHYL BENZENE

100-41-4

ACGIH - Short Term Exposure Limits

NAPHTHALENE

91-20-3

ACGIH - Short Term Exposure Limits

XYLENE

1330-20-7

ACGIH - Skin Absorption Designation

BENZENE

71-43-2

ACGIH - Skin Absorption Designation

N-HEXANE

110-54-3

ACGIH - Skin Absorption Designation

NAPHTHALENE

91-20-3

ACGIH - Skin Absorption Designation

TOLUENE

108-88-3

CAA (Clean Air Act) - High Risk Haz Air Pollutants

BENZENE

71-43-2

CAA (Clean Air Act) - HON Rule - Organic HAPs

BENZENE

71-43-2

CAA (Clean Air Act) - HON Rule - Organic HAPs

ETHYL BENZENE

100-41-4

CAA (Clean Air Act) - HON Rule - Organic HAPs

N-HEXANE

110-54-3

CAA (Clean Air Act) - HON Rule - Organic HAPs

NAPHTHALENE

91-20-3

CAA (Clean Air Act) - HON Rule - Organic HAPs

TOLUENE

108-88-3

CAA (Clean Air Act) - HON Rule - Organic HAPs

XYLENE

1330-20-7

CAA (Clean Air Act) - HON Rule - SOCMI Chemicals

BENZENE

71-43-2

CAA (Clean Air Act) - HON Rule - SOCMI Chemicals

CYCLOHEXANE

110-82-7

CAA (Clean Air Act) - HON Rule - SOCMI Chemicals

ETHYL BENZENE

100-41-4

CAA (Clean Air Act) - HON Rule - SOCMI Chemicals

N-HEXANE

110-54-3

CAA (Clean Air Act) - HON Rule - SOCMI Chemicals

NAPHTHALENE

91-20-3

CAA (Clean Air Act) - HON Rule - SOCMI Chemicals

TOLUENE

108-88-3

CAA (Clean Air Act) - HON Rule - SOCMI Chemicals

XYLENE

1330-20-7

CAA (Clean Air Act) - VOCs in SOCMI

BENZENE

71-43-2

CAA (Clean Air Act) - VOCs in SOCMI

CYCLOHEXANE

110-82-7

CAA (Clean Air Act) - VOCs in SOCMI

ETHYL ALCOHOL

64-17-5

CAA (Clean Air Act) - VOCs in SOCMI

ETHYL BENZENE

100-41-4

CAA (Clean Air Act) - VOCs in SOCMI

TOLUENE

108-88-3

CAA (Clean Air Act) - VOCs in SOCMI

XYLENE

1330-20-7

CAA - 1990 Hazardous Air Pollutants

BENZENE

71-43-2

CAA - 1990 Hazardous Air Pollutants

ETHYL BENZENE

100-41-4

CAA - 1990 Hazardous Air Pollutants

N-HEXANE

110-54-3

CAA - 1990 Hazardous Air Pollutants

NAPHTHALENE

91-20-3

CAA - 1990 Hazardous Air Pollutants

TOLUENE

108-88-3

CAA - 1990 Hazardous Air Pollutants

XYLENE

1330-20-7

California - Prop. 65 - Developmental Toxicity

BENZENE

71-43-2

California - Prop. 65 - Developmental Toxicity

ETHYL ALCOHOL

64-17-5

California - Prop. 65 - Developmental Toxicity

TOLUENE

108-88-3

California - Prop. 65 - Reproductive - Male

BENZENE

71-43-2

California - Proposition 65 - Carcinogens List

BENZENE

71-43-2

California - Proposition 65 - Carcinogens List

ETHYL BENZENE

100-41-4

California - Proposition 65 - Carcinogens List

NAPHTHALENE

91-20-3

Canada - CEPA - Sch. I - List of Toxic Substances

BENZENE

71-43-2

Canada - WHMIS - Ingredient Disclosure

1,2,4-TRIMETHYLBENZENE

95-63-6

Canada - WHMIS - Ingredient Disclosure

BENZENE

71-43-2

Canada - WHMIS - Ingredient Disclosure

CYCLOHEXANE

110-82-7

Canada - WHMIS - Ingredient Disclosure

ETHYL ALCOHOL

64-17-5

Canada - WHMIS - Ingredient Disclosure

ETHYL BENZENE

100-41-4

Canada - WHMIS - Ingredient Disclosure

N-BUTANE

106-97-8

Canada - WHMIS - Ingredient Disclosure

N-HEXANE

110-54-3

Canada - WHMIS - Ingredient Disclosure

NAPHTHALENE

91-20-3

Canada - WHMIS - Ingredient Disclosure

TOLUENE

108-88-3

CERCLA/SARA - Haz Substances and their RQs

BENZENE

71-43-2

CERCLA/SARA - Haz Substances and their RQs

CYCLOHEXANE

110-82-7

CERCLA/SARA - Haz Substances and their RQs

ETHYL BENZENE

100-41-4

CERCLA/SARA - Haz Substances and their RQs

N-HEXANE

110-54-3

CERCLA/SARA - Haz Substances and their RQs

NAPHTHALENE

91-20-3

CERCLA/SARA - Haz Substances and their RQs

TOLUENE

108-88-3

CERCLA/SARA - Haz Substances and their RQs

XYLENE

1330-20-7

CERCLA/SARA - Section 313 - Emission Reporting

1,2,4-TRIMETHYLBENZENE

95-63-6

CERCLA/SARA - Section 313 - Emission Reporting

BENZENE

71-43-2

CERCLA/SARA - Section 313 - Emission Reporting

CYCLOHEXANE

110-82-7

CERCLA/SARA - Section 313 - Emission Reporting

ETHYL BENZENE

100-41-4

CERCLA/SARA - Section 313 - Emission Reporting

N-HEXANE

110-54-3

CERCLA/SARA - Section 313 - Emission Reporting

NAPHTHALENE

91-20-3

CERCLA/SARA - Section 313 - Emission Reporting

TOLUENE

108-88-3

CERCLA/SARA - Section 313 - Emission Reporting

XYLENE

1330-20-7

CWA (Clean Water Act) - Hazardous Substances

BENZENE

71-43-2

CWA (Clean Water Act) - Hazardous Substances

CYCLOHEXANE

110-82-7

CWA (Clean Water Act) - Hazardous Substances

ETHYL BENZENE

100-41-4

CWA (Clean Water Act) - Hazardous Substances

NAPHTHALENE

91-20-3

CWA (Clean Water Act) - Hazardous Substances

TOLUENE

108-88-3

CWA (Clean Water Act) - Hazardous Substances

XYLENE

1330-20-7

CWA (Clean Water Act) - Priority Pollutants

BENZENE

71-43-2

CWA (Clean Water Act) - Priority Pollutants

ETHYL BENZENE

100-41-4

CWA (Clean Water Act) - Priority Pollutants

NAPHTHALENE

91-20-3

CWA (Clean Water Act) - Priority Pollutants

TOLUENE

108-88-3

CWA (Clean Water Act) - Toxic Pollutants

BENZENE

71-43-2

CWA (Clean Water Act) - Toxic Pollutants

ETHYL BENZENE

100-41-4

CWA (Clean Water Act) - Toxic Pollutants

NAPHTHALENE

91-20-3

CWA (Clean Water Act) - Toxic Pollutants

TOLUENE

108-88-3

DEA - List II Essential Chemicals

TOLUENE

108-88-3

IARC - Group 1 (carcinogenic to humans)

BENZENE

71-43-2

IARC - Group 2B (Possibly carcinogenic to humans)

ETHYL BENZENE

100-41-4

IARC - Group 2B (Possibly carcinogenic to humans)

NAPHTHALENE

91-20-3

IARC - Group 3 (not classifiable)

TOLUENE

108-88-3

IARC - Group 3 (not classifiable)

XYLENE

1330-20-7

Inventory - Australia (AICS)

1,2,4-TRIMETHYLBENZENE

95-63-6

Inventory - Australia (AICS)

ALKYLATE

64741-66-8

Inventory - Australia (AICS)

BENZENE

71-43-2

Inventory - Australia (AICS)

CYCLOHEXANE

110-82-7

Inventory - Australia (AICS)

ETHYL ALCOHOL

64-17-5

Inventory - Australia (AICS)

ETHYL BENZENE

100-41-4

Inventory - Australia (AICS)

N-BUTANE

106-97-8

Inventory - Australia (AICS)

N-HEXANE

110-54-3

Inventory - Australia (AICS)

NAPHTHALENE

91-20-3

Inventory - Australia (AICS)

TOLUENE

108-88-3

Inventory - Australia (AICS)

XYLENE

1330-20-7

Inventory - Canada - Domestic Substances List

1,2,4-TRIMETHYLBENZENE

95-63-6

Inventory - Canada - Domestic Substances List

ALKYLATE

64741-66-8

Inventory - Canada - Domestic Substances List

BENZENE

71-43-2

Inventory - Canada - Domestic Substances List

CYCLOHEXANE

110-82-7

Inventory - Canada - Domestic Substances List

ETHYL ALCOHOL

64-17-5

Inventory - Canada - Domestic Substances List

ETHYL BENZENE

100-41-4

Inventory - Canada - Domestic Substances List

N-BUTANE

106-97-8

Inventory - Canada - Domestic Substances List

N-HEXANE

110-54-3

Inventory - Canada - Domestic Substances List

NAPHTHALENE

91-20-3

Inventory - Canada - Domestic Substances List

TOLUENE

108-88-3

Inventory - Canada - Domestic Substances List

XYLENE

1330-20-7

Inventory - China

1,2,4-TRIMETHYLBENZENE

95-63-6

Inventory - China

ALKYLATE

64741-66-8

Inventory - China

BENZENE

71-43-2

Inventory - China

CYCLOHEXANE

110-82-7

Inventory - China

ETHYL ALCOHOL

64-17-5

Inventory - China

ETHYL BENZENE

100-41-4

Inventory - China

N-BUTANE

106-97-8

Inventory - China

N-HEXANE

110-54-3

Inventory - China

NAPHTHALENE

91-20-3

Inventory - China

TOLUENE

108-88-3

Inventory - China

XYLENE

1330-20-7

Inventory - European EINECS Inventory

1,2,4-TRIMETHYLBENZENE

95-63-6

Inventory - European EINECS Inventory

ALKYLATE

64741-66-8

Inventory - European EINECS Inventory

BENZENE

71-43-2

Inventory - European EINECS Inventory

CYCLOHEXANE

110-82-7

Inventory - European EINECS Inventory

ETHYL ALCOHOL

64-17-5

Inventory - European EINECS Inventory

ETHYL BENZENE

100-41-4

Inventory - European EINECS Inventory

N-BUTANE

106-97-8

Inventory - European EINECS Inventory

N-HEXANE

110-54-3

Inventory - European EINECS Inventory

NAPHTHALENE

91-20-3

Inventory - European EINECS Inventory

TOLUENE

108-88-3

Inventory - European EINECS Inventory

XYLENE

1330-20-7

Inventory - Japan - (ENCS)

1,2,4-TRIMETHYLBENZENE

95-63-6

Inventory - Japan - (ENCS)

BENZENE

71-43-2

Inventory - Japan - (ENCS)

CYCLOHEXANE

110-82-7

Inventory - Japan - (ENCS)

ETHYL ALCOHOL

64-17-5

Inventory - Japan - (ENCS)

ETHYL BENZENE

100-41-4

Inventory - Japan - (ENCS)

N-BUTANE

106-97-8

Inventory - Japan - (ENCS)

N-HEXANE

110-54-3

Inventory - Japan - (ENCS)

NAPHTHALENE

91-20-3

Inventory - Japan - (ENCS)

TOLUENE

108-88-3

Inventory - Japan - (ENCS)

XYLENE

1330-20-7

Inventory - Korea - Existing and Evaluated

1,2,4-TRIMETHYLBENZENE

95-63-6

Inventory - Korea - Existing and Evaluated

ALKYLATE

64741-66-8

Inventory - Korea - Existing and Evaluated

BENZENE

71-43-2

Inventory - Korea - Existing and Evaluated

CYCLOHEXANE

110-82-7

Inventory - Korea - Existing and Evaluated

ETHYL ALCOHOL

64-17-5

Inventory - Korea - Existing and Evaluated

ETHYL BENZENE

100-41-4

Inventory - Korea - Existing and Evaluated

N-BUTANE

106-97-8

Inventory - Korea - Existing and Evaluated

N-HEXANE

110-54-3

Inventory - Korea - Existing and Evaluated

NAPHTHALENE

91-20-3

Inventory - Korea - Existing and Evaluated

TOLUENE

108-88-3

Inventory - Korea - Existing and Evaluated

XYLENE

1330-20-7

Inventory - New Zealand

1,2,4-TRIMETHYLBENZENE

95-63-6

Inventory - New Zealand

ALKYLATE

64741-66-8

Inventory - New Zealand

BENZENE

71-43-2

Inventory - New Zealand

CYCLOHEXANE

110-82-7

Inventory - New Zealand

ETHYL ALCOHOL

64-17-5

Inventory - New Zealand

ETHYL BENZENE

100-41-4

Inventory - New Zealand

N-BUTANE

106-97-8

Inventory - New Zealand

N-HEXANE

110-54-3

Inventory - New Zealand

NAPHTHALENE

91-20-3

Inventory - New Zealand

TOLUENE

108-88-3

Inventory - New Zealand

XYLENE

1330-20-7

Inventory - Philippines Inventory (PICCS)

1,2,4-TRIMETHYLBENZENE

95-63-6

Inventory - Philippines Inventory (PICCS)

ALKYLATE

64741-66-8

Inventory - Philippines Inventory (PICCS)

BENZENE

71-43-2

Inventory - Philippines Inventory (PICCS)

CYCLOHEXANE

110-82-7

Inventory - Philippines Inventory (PICCS)

ETHYL ALCOHOL

64-17-5

Inventory - Philippines Inventory (PICCS)

ETHYL BENZENE

100-41-4

Inventory - Philippines Inventory (PICCS)

N-BUTANE

106-97-8

Inventory - Philippines Inventory (PICCS)

N-HEXANE

110-54-3

Inventory - Philippines Inventory (PICCS)

NAPHTHALENE

91-20-3

Inventory - Philippines Inventory (PICCS)

TOLUENE

108-88-3

Inventory - Philippines Inventory (PICCS)

XYLENE

1330-20-7

Inventory - TSCA - Sect. 8(b) Inventory

1,2,4-TRIMETHYLBENZENE

95-63-6

Inventory - TSCA - Sect. 8(b) Inventory

ALKYLATE

64741-66-8

Inventory - TSCA - Sect. 8(b) Inventory

BENZENE

71-43-2

Inventory - TSCA - Sect. 8(b) Inventory

CYCLOHEXANE

110-82-7

Inventory - TSCA - Sect. 8(b) Inventory

ETHYL ALCOHOL

64-17-5

Inventory - TSCA - Sect. 8(b) Inventory

ETHYL BENZENE

100-41-4

Inventory - TSCA - Sect. 8(b) Inventory

N-BUTANE

106-97-8

Inventory - TSCA - Sect. 8(b) Inventory

N-HEXANE

110-54-3

Inventory - TSCA - Sect. 8(b) Inventory

NAPHTHALENE

91-20-3

Inventory - TSCA - Sect. 8(b) Inventory

TOLUENE

108-88-3

Inventory - TSCA - Sect. 8(b) Inventory

XYLENE

1330-20-7

Massachusetts - Right To Know List

1,2,4-TRIMETHYLBENZENE

95-63-6

Massachusetts - Right To Know List

BENZENE

71-43-2

Massachusetts - Right To Know List

CYCLOHEXANE

110-82-7

Massachusetts - Right To Know List

ETHYL ALCOHOL

64-17-5

Massachusetts - Right To Know List

ETHYL BENZENE

100-41-4

Massachusetts - Right To Know List

N-BUTANE

106-97-8

Massachusetts - Right To Know List

N-HEXANE

110-54-3

Massachusetts - Right To Know List

NAPHTHALENE

91-20-3

Massachusetts - Right To Know List

TOLUENE

108-88-3

Massachusetts - Right To Know List

XYLENE

1330-20-7

New Jersey - Department of Health RTK List

1,2,4-TRIMETHYLBENZENE

95-63-6

New Jersey - Department of Health RTK List

BENZENE

71-43-2

New Jersey - Department of Health RTK List

CYCLOHEXANE

110-82-7

New Jersey - Department of Health RTK List

ETHYL ALCOHOL

64-17-5

New Jersey - Department of Health RTK List

ETHYL BENZENE

100-41-4

New Jersey - Department of Health RTK List

N-BUTANE

106-97-8

New Jersey - Department of Health RTK List

N-HEXANE

110-54-3

New Jersey - Department of Health RTK List

NAPHTHALENE

91-20-3

New Jersey - Department of Health RTK List

TOLUENE

108-88-3

New Jersey - Department of Health RTK List

XYLENE

1330-20-7

New Jersey - Env Hazardous Substances List

1,2,4-TRIMETHYLBENZENE

95-63-6

New Jersey - Env Hazardous Substances List

BENZENE

71-43-2

New Jersey - Env Hazardous Substances List

CYCLOHEXANE

110-82-7

New Jersey - Env Hazardous Substances List

ETHYL BENZENE

100-41-4

New Jersey - Env Hazardous Substances List

N-BUTANE

106-97-8

New Jersey - Env Hazardous Substances List

N-HEXANE

110-54-3

New Jersey - Env Hazardous Substances List

NAPHTHALENE

91-20-3

New Jersey - Env Hazardous Substances List

TOLUENE

108-88-3

New Jersey - Env Hazardous Substances List

XYLENE

1330-20-7

New Jersey - Special Hazardous Substances

BENZENE

71-43-2

New Jersey - Special Hazardous Substances

CYCLOHEXANE

110-82-7

New Jersey - Special Hazardous Substances

ETHYL ALCOHOL

64-17-5

New Jersey - Special Hazardous Substances

ETHYL BENZENE

100-41-4

New Jersey - Special Hazardous Substances

N-BUTANE

106-97-8

New Jersey - Special Hazardous Substances

N-HEXANE

110-54-3

New Jersey - Special Hazardous Substances

TOLUENE

108-88-3

New Jersey - Special Hazardous Substances

XYLENE

1330-20-7

NTP - Report on Carcinogens - Known Carcinogens

BENZENE

71-43-2

NTP - Report on Carcinogens - Suspect Carcinogens

NAPHTHALENE

91-20-3

OSHA - Final PELs - Ceiling Limits

BENZENE

71-43-2

OSHA - Final PELs - Ceiling Limits

TOLUENE

108-88-3

OSHA - Final PELs - Short Term Exposure Limits

BENZENE

71-43-2

OSHA - Final PELs - Time Weighted Averages

BENZENE

71-43-2

OSHA - Final PELs - Time Weighted Averages

CYCLOHEXANE

110-82-7

OSHA - Final PELs - Time Weighted Averages

ETHYL ALCOHOL

64-17-5

OSHA - Final PELs - Time Weighted Averages

ETHYL BENZENE

100-41-4

OSHA - Final PELs - Time Weighted Averages

N-HEXANE

110-54-3

OSHA - Final PELs - Time Weighted Averages

NAPHTHALENE

91-20-3

OSHA - Final PELs - Time Weighted Averages

TOLUENE

108-88-3

OSHA - Final PELs - Time Weighted Averages

XYLENE

1330-20-7

OSHA - Hazard Communication Carcinogens

BENZENE

71-43-2

OSHA - Specifically Regulated Carcinogens

BENZENE

71-43-2

Pennsylvania - RTK (Right to Know) List

1,2,4-TRIMETHYLBENZENE

95-63-6

Pennsylvania - RTK (Right to Know) List

BENZENE

71-43-2

Pennsylvania - RTK (Right to Know) List

CYCLOHEXANE

110-82-7

Pennsylvania - RTK (Right to Know) List

ETHYL ALCOHOL

64-17-5

Pennsylvania - RTK (Right to Know) List

ETHYL BENZENE

100-41-4

Pennsylvania - RTK (Right to Know) List

N-BUTANE

106-97-8

Pennsylvania - RTK (Right to Know) List

N-HEXANE

110-54-3

Pennsylvania - RTK (Right to Know) List

NAPHTHALENE

91-20-3

Pennsylvania - RTK (Right to Know) List

TOLUENE

108-88-3

Pennsylvania - RTK (Right to Know) List

XYLENE

1330-20-7

Pennsylvania - RTK - Environmental Hazard List

1,2,4-TRIMETHYLBENZENE

95-63-6

Pennsylvania - RTK - Environmental Hazard List

BENZENE

71-43-2

Pennsylvania - RTK - Environmental Hazard List

CYCLOHEXANE

110-82-7

Pennsylvania - RTK - Environmental Hazard List

ETHYL BENZENE

100-41-4

Pennsylvania - RTK - Environmental Hazard List

NAPHTHALENE

91-20-3

Pennsylvania - RTK - Environmental Hazard List

TOLUENE

108-88-3

Pennsylvania - RTK - Environmental Hazard List

XYLENE

1330-20-7

Pennsylvania - RTK - Special Hazardous Substances

BENZENE

71-43-2

TSCA - Sect. 12(b) - Export Notification

CYCLOHEXANE

110-82-7

TSCA - Sect. 12(b) - Export Notification

N-HEXANE

110-54-3

TSCA - Sect. 12(b) - Export Notification

NAPHTHALENE

91-20-3

TSCA - Section 4 - Chemical Test Rules

CYCLOHEXANE

110-82-7

TSCA - Section 4 - Chemical Test Rules

NAPHTHALENE

91-20-3

U.S. - DOT - Hazardous Substances and RQs (App A)

BENZENE

71-43-2

U.S. - DOT - Hazardous Substances and RQs (App A)

CYCLOHEXANE

110-82-7

U.S. - DOT - Hazardous Substances and RQs (App A)

ETHYL BENZENE

100-41-4

U.S. - DOT - Hazardous Substances and RQs (App A)

N-HEXANE

110-54-3

U.S. - DOT - Hazardous Substances and RQs (App A)

NAPHTHALENE

91-20-3

U.S. - DOT - Hazardous Substances and RQs (App A)

TOLUENE

108-88-3

U.S. - DOT - Hazardous Substances and RQs (App A)

XYLENE

1330-20-7

 

 

Title III Classifications Sections 311,312:

 

         Acute: YES

         Chronic: YES

         Fire: YES

         Reactivity: NO

         Sudden Release of Pressure: NO

 

 

15. OTHER INFORMATION

Follow all MSDS/label precautions even after container is emptied because it may retain product residue. Keep out of reach of children. Precautionary labeling for pumps, portable containers, and drums is required. A "hazardous when empty" pictogram and D.O.T. flammable liquid label are also required for drums. Details available upon request. Because benzene is present in this product above 0.1%, the Osha Standard for benzene is applicable to work locations upstream of final discharge from terminals. Consult 29CFR1910.1028 for details. Prolonged and repeated excessive exposures to benzene can result in blood disorders ranging from anemia to leukemia. Sun recommends that exposures to benzene be kept below 0.5 ppm for 8-hours; 2.5 ppm for 15-min. Normal service station operations are below these values. For use as motor fuel only. Do not use for any other purpose. NOTE TO PHYSICIAN: Catecholamines and similar adrenergic drugs are generally contraindicated because of potential for increased sensitivity of the heart from hydrocarbon overexposure and subsequent ventricular fibrillation. EKG monitoring may be indicated and bronchodilators should be selected with care. Following injection, prompt debridement of the wound is necessary to minimize necrosis and tissue loss. COMPONENT TOXICITY: Overexposure to naphthalene, a minor component of this product, may cause skin, eye and respiratory tract irritation, anemia, loss of vision, nervous system effects and kidney and thymus damage. Also, exposure to naphthalene has produced "respiratory tract" tumors in laboratory animals.. Ethylbenzene, a component of this product, has been designated by the International Agency for Research on Cancer as "possibly carcinogenic to humans", based on increased tumor incidence in laboratory animals. Overexposure may lead to nervous system effects, including drowsiness, dizziness, nausea, headaches, paralysis, loss of consciousness and even death. Repeated overexposure has caused a hearing loss in laboratory animals. Hours of exposure to high airborne concentrations of xylene, a minor component of this product, has caused a hearing loss in laboratory animals.