|
|
MATERIAL SAFETY
DATA SHEET
1. CHEMICAL PRODUCT AND COMPANY INFORMATION
Product Name: SUNOCO FR
Manufacturer Information:
|
Sunoco, Inc. (R&M) |
|
1735 Market Street LL |
|
|
|
Philadelphia, Pennsylvania,
19103-7583 |
Product Use:
|
Racing fuel |
Emergency Phone Numbers:
|
Chemtrec |
(800) 424-9300 |
|
|
Sunoco Inc. |
(800) 964-8861 |
|
Information:
|
Product Safety Information |
(888) 567-3066 |
2. COMPOSITION/INFORMATION ON INGREDIENTS
Component
|
CAS No.
|
Amount (Vol%)
|
|
|
ALKYLATE |
64741-66-8 |
50
- 60 |
|
|
TOLUENE |
108-88-3 |
25
- 35 |
|
|
ETHYL ALCOHOL |
64-17-5 |
10.2
- 10.2 |
|
|
N-BUTANE |
106-97-8 |
9
- 9 |
|
|
N-HEXANE |
110-54-3 |
1
- 2 |
|
|
XYLENE |
1330-20-7 |
0.5
- 1.5 |
|
|
1,2,4-TRIMETHYLBENZENE |
95-63-6 |
0.4
- 0.5 |
|
|
ETHYL BENZENE |
100-41-4 |
0.1
- 0.2 |
|
|
BENZENE |
71-43-2 |
0.1
- 0.15 |
|
|
CYCLOHEXANE |
110-82-7 |
0.05
- 0.1 |
|
|
NAPHTHALENE |
91-20-3 |
0.05
- 0.1 |
|
EXPOSURE GUIDELINES (SEE SECTION 15 FOR ADDITIONAL EXPOSURE LIMITS)
|
|
CAS No.
|
Governing Body
|
Exposure Limits
|
|
ALKYLATE |
64741-66-8 |
Sunoco |
TWA |
100 |
ppm |
|
BENZENE |
71-43-2 |
ACGIH |
STEL |
2.5 |
ppm |
|
BENZENE |
71-43-2 |
OSHA |
STEL |
5 |
ppm |
|
BENZENE |
71-43-2 |
ACGIH |
TWA |
0.5 |
ppm |
|
BENZENE |
71-43-2 |
OSHA |
TWA |
1 |
ppm |
|
CYCLOHEXANE |
110-82-7 |
ACGIH |
TWA |
100 |
ppm |
|
CYCLOHEXANE |
110-82-7 |
OSHA |
TWA |
300 |
ppm |
|
ETHYL ALCOHOL |
64-17-5 |
ACGIH |
TWA |
1000 |
ppm |
|
ETHYL ALCOHOL |
64-17-5 |
OSHA |
TWA |
1000 |
ppm |
|
ETHYL BENZENE |
100-41-4 |
ACGIH |
STEL |
125 |
ppm |
|
ETHYL BENZENE |
100-41-4 |
ACGIH |
TWA |
100 |
ppm |
|
ETHYL BENZENE |
100-41-4 |
OSHA |
TWA |
100 |
ppm |
|
N-BUTANE |
106-97-8 |
ACGIH |
TWA |
1000 |
ppm |
|
N-HEXANE |
110-54-3 |
ACGIH |
TWA |
50 |
ppm |
|
N-HEXANE |
110-54-3 |
OSHA |
TWA |
500 |
ppm |
|
NAPHTHALENE |
91-20-3 |
ACGIH |
STEL |
15 |
ppm |
|
NAPHTHALENE |
91-20-3 |
ACGIH |
TWA |
10 |
ppm |
|
NAPHTHALENE |
91-20-3 |
OSHA |
TWA |
10 |
ppm |
|
TOLUENE |
108-88-3 |
NIOSH |
STEL |
150 |
ppm |
|
TOLUENE |
108-88-3 |
ACGIH |
TWA |
20 |
ppm |
|
TOLUENE |
108-88-3 |
OSHA |
TWA |
200 |
ppm |
|
XYLENE |
1330-20-7 |
ACGIH |
STEL |
150 |
ppm |
|
XYLENE |
1330-20-7 |
ACGIH |
TWA |
100 |
ppm |
|
XYLENE |
1330-20-7 |
OSHA |
TWA |
100 |
ppm |
3. HAZARDS IDENTIFICATION
· EMERGENCY OVERVIEW
Danger!
Extremely flammable liquid and vapor.
Vapors may cause flash fire or explosion. Static accumulator. May form an ignitable
vapor/air mixture. Excessive exposure to
mists or vapors generated by heat may cause irritation to eyes, nose, throat,
lungs and respiratory tract. Harmful or
fatal if swallowed. Pulmonary aspiration
hazard. While ingesting or vomiting, may
enter lungs and produce damage. Harmful
if inhaled. Overexposure may lead to
serious disturbances of heart rhythm and nervous system effects, including
drowsiness, dizziness, nausea, headaches,
paralysis, loss of consciousness
and even death. May cause skin
irritation. May cause eye
irritation. Contains material or
materials that can cause birth defects.
Contains material or materials that can cause cancer. May cause target organ or system damage to
the following: eye, central nervous system, kidney,
liver, respiratory system, skin,
cardiovascular system, heart, peripheral nervous system, bone marrow,
Hazards Ratings:
Key: 0 = least, 1 = slight, 2 =
moderate, 3 = high, 4 = extreme
|
|
Health
|
Fire
|
Reactivity
|
PPI
|
|
NFPA |
1 |
3 |
0 |
|
|
HMIS |
2 |
3 |
0 |
X |
· POTENTIAL HEALTH EFFECTS
§ PRE-EXISTING MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE
The
following diseases or disorders may be aggravated by exposure to this
product: skin, eye,
blood forming organs, nervous
system, respiratory system, lung (asthma-like conditions), cardiovascular system,
§ INHALATION
High concentrations may lead to central
nervous system effects (drowsiness, dizziness, nausea, headaches, paralysis and
loss of consciousness and even death).
May cause serious disturbances of heart rhythm. Excessive exposure to mists or vapors
generated by heat may cause irritation to eyes, nose, throat, lungs and
respiratory tract. Solvent "huffing/sniffing"
(abuse) or intentional prolonged overexposure to high levels of vapors can
produce abnormal behavior, convulsions, hallucinations, delerium, nervous
system damage, serious disturbances of heart rhythm and sudden death. Repeated excessive exposures may cause blood
disorders such as anemia and leukemia.
Contains a material that has been related to cancer in humans.
|
LC50
(mg/l): |
no data |
|
|
LC50
(mg/m3): |
no data |
|
|
LC50 (ppm): |
no data |
|
§ SKIN
Moderately irritating to the skin. Prolonged or repeated contact can result in
defatting and drying of the skin which may result in skin irritation and
dermatitis (rash).
|
Draize Skin Score: |
no data |
|
Out
of 8.0 |
|
|
LD50 (mg/kg): |
no data |
|
§ EYES
Moderately irritating to the eyes. Contact with the eye may cause redness,
burning, tearing and/or blurred vision.
§ INGESTION
Harmful or fatal if swallowed. Pulmonary aspiration hazard. While ingesting or vomiting, may enter lungs
and produce damage. Irritating to mouth,
throat, and stomach. Contains material
or materials that can cause birth defects.
May produce central nervous system effects, which includes dizziness,
loss of balance and coordination, unconsciousness, coma and even death.
|
LD50
(g/kg): |
no data |
|
4. FIRST AID MEASURES
· INHALATION
Remove to fresh air. If not breathing, give artificial
respiration. If breathing is difficult,
give oxygen and continue to monitor. Get
immediate medical attention.
· SKIN
Immediately flush with large amounts of
water for 20 minutes, use soap if available.
Remove contaminated clothing, including shoes, after flushing has
begun. Get prompt medical
attention. Injection injuries may not
appear serious at first but within a few hours, without proper treatment, the
area will become swollen, discolored and extremely painful. Wash clothing before reuse.
· EYES
Flush eye with water for 20
minutes. Get medical attention.
· INGESTION
If swallowed, immediately contact a
physician or Poison Control Center.
Never give anything by mouth to an intoxicated, unconscious or convulsing
person. Get immediate medical
attention. Do not induce vomiting!
5. FIRE FIGHTING MEASURES
· EXTINGUISHING MEDIA
The
following media may be used to extinguish a fire involving this material: Alcohol resistant foam;
· FIRE FIGHTING INSTRUCTIONS
Use water spray to cool fire exposed
tanks and containers. Wear structural
fire fighting gear. The use of fresh air
equipment such as Self Contained Breathing Apparatus (SCBA) or Supplied Air
Respirators should be worn for fire fighting if exposure or potential exposure
to products of combustion is expected.
· FLAMMABLE PROPERTIES
Flammable liquid and vapor. STATIC ACCUMULATOR. This liquid may form an ignitable vapor-air
mixture in closed tanks or containers.
|
|
Typical
|
Minimum
|
Maximum
|
Text Result
|
Units
|
Method
|
|
Flash Point |
|
|
|
Minus 40 est'd |
F |
N/A |
|
Autoignition
Temperature |
|
|
|
536 estimated |
F |
N/A |
|
Lower Explosion Limit |
1.5 |
|
|
|
% |
N/A |
|
Upper Explosion Limit |
7.6 |
|
|
|
% |
N/A |
6. ACCIDENTAL RELEASE MEASURES
Prevent ignition, stop leak and
ventilate the area. Contain spilled
liquid with sand or earth. DO NOT use
combustible materials such as sawdust.
Absorb spill with inert material (e.g., dry sand or earth), then place
in a chemical waste container. Do not
use spark-generating metals for sweeping up spilled material. Avoid runoff into storm sewers and ditches
which lead to waterways. Vapor can be
controlled using a water fog. Water
streams should not be directed to the liquid as this will cause the liquid to
boil and generate more vapor. Keep personnel
upwind from leak. Use appropriate
personal protective equipment as stated in Section 8 of this MSDS. Advise the Environmental Protection Agency
(EPA) and appropriate state agencies, if required. Vacuum or sweep up material and place in a
disposal container.
7. HANDLING AND STORAGE
·
HANDLING
Follow all MSDS/label precautions even
after container is emptied because it may retain product residue. STATIC ACCUMULATOR. This liquid may form an ignitable vapor-air
mixture in closed tanks or containers.
This liquid may accumulate static electricity even when transferred into
properly grounded containers. Bonding
and grounding may be insufficient to remove static electricity. Static electricity accumulation may be
significantly increased by the presence of small quantities of water.Always
bond receiving container to the fill pipe before and during loading, following
NFPA-77 and/or API RP 2003 requirements.
Automatic gauging devices and other floats in vessels or tanks which
contain static accumulating liquids should be electrically bonded to the
shell. Bonding and grounding alone may
be inadequate to eliminate fire and explosion hazards associated with
electrostatic charges. In addition to
bonding and grounding, efforts to mitigate the hazards of an electrostatic
discharge may include, but are not limited to, ventilation, inerting and/or
reduction of transfer velocities. Always keep the nozzle in contact with the
container throughout the loading process.
Do not fill any portable containers in or on a vehicle. Special precautions, such as reduced loading
rates and increased monitoring, must be observed during "switch
loading" operations (i.e. loading this material in tanks or shipping
compartments that previously contained middle distillates or similar
products). Non-equilibrium conditions
may increase the risks associated with static electricity such as tank and
container filling, tank cleaning, sampling, gauging, loading, filtering,
mixing, agitation, etc. Dissipation of
electrostatic charges may be improved with the use of conductivity additives
when used with other mitigating efforts, including bonding and grounding. Avoid breathing (dust, vapor, mist,
gas). Use only in a well-ventilated
area. Avoid contact with eyes, skin, and
clothing. Wash thoroughly after
handling. Never siphon by mouth. "Empty" containers retain product
residue (liquid and/or vapor) and can be dangerous. DO NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER,
DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC
ELECTRICITY, OR OTHER SOURCES OF IGNITION.
THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. Empty drums should be completely drained,
properly bunged, and promptly returned to a drum reconditioned, or properly
disposed of.
·
STORAGE
Keep away from heat, sparks, and
flame. Keep container closed when not in
use. Consult NFPA and / or OSHA codes
for additional information. Store in a
cool dry place. NFPA class IB
storage. Flash point is less than 73
degrees F and boiling point is greater than or equal to 100 degrees F. Outside or detached storage is preferred.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Consult With a Health and Safety
Professional for Specific Selections
· ENGINEERING CONTROLS
Use process enclosures, local exhaust
ventilation, or other engineering controls to control airborne levels below
recommended exposure limits. Use with
adequate ventilation. Local exhaust
ventilation may be necessary to control any air contaminants to within their
TLVs during the use of this product. Use
explosion-proof ventilation equipment.
Facilities storing or utilizing this material should be equipped with an
eyewash facility and a safety shower.
· PERSONAL PROTECTION
§ EYE PROTECTION
Use chemical splash goggles and face
shield (ANSI Z87.1 or approved equivalent).
§ GLOVES or HAND PROTECTION
The glove(s) listed below may provide
protection against permeation. Gloves of
other chemically resistant materials may not provide adequate protection. Protective gloves are recommended to protect
against contact with product.
Nitrile; Viton; Teflon;
§ RESPIRATORY PROTECTION
Concentration
in air determines the level of respiratory protection needed. Use only NIOSH certified respiratory
equipment. Half-mask air purifying
respirator with organic vapor cartridges is acceptable for exposures to ten
(10) times the exposure limit. Full-face
air purifying respirator with organic vapor cartridges is acceptable for
exposures to fifty (50) times the exposure limit. Exposure should not exceed the cartridge
limit of 1000 ppm. Protection by air
purifying respirators is limited. Use a
positive pressure-demand full-face supplied air respirator or SCBA for
exposures greater than fifty (50) times the exposure limit. If exposure is above the IDLH (Immediately
Dangerous to Life and Health) or there is the possibility of an uncontrolled
release, or exposure levels are unknown, then use a positive pressure-demand
full-face supplied air respirator with escape bottle or SCBA. Wear a NIOSH-approved (or equivalent)
full-facepiece airline respirator in the positive pressure mode with emergency
escape provisions.
§ OTHER
Where
splashing is possible, full chemically resistant protective clothing and boots
are required. The following materials
are acceptable for use as protective clothing:
Nitrile; Viton; Teflon;
Facilities storing or utilizing this material should be equipped with an
eyewash facility and a safety shower.
Remove contaminated clothing and wash before reuse. For non-fire emergencies, positive pressure
SCBA and structural firefighter's protective clothing will provide only limited
protection.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical Property
|
Typical
|
Units
|
Text Result
|
Reference
|
|
Appearance |
|
N/A |
Clear liquid |
|
|
Boiling Point |
|
F |
100 - 430 |
|
|
Bulk Density |
6.16 |
lb/gal |
|
|
|
Liquid Conductivity |
|
pS/m |
< 50 (varies) |
|
|
Melting Point |
|
F |
no data |
|
|
Molecular Weight |
|
g/mole |
no data |
|
|
Octanol/Water Coefficient |
|
N/A |
no data |
|
|
pH |
|
N/A |
no data |
|
|
Specific Gravity |
0.74 |
N/A |
|
|
|
Solubility In Water |
|
wt % |
Nil to 15% |
|
|
Odor |
|
N/A |
Gasoline odor |
|
|
Odor Threshold |
|
ppm |
< 1 |
|
|
Vapor Pressure |
|
psia |
5 - 16 |
|
|
Viscosity (F) |
|
SUS |
no data |
|
|
Viscosity (C) |
|
CsT |
no data |
|
|
% Volatile |
100 |
wt % |
|
|
10. STABILITY AND REACTIVITY
· STABILITY
Stable
· CONDITIONS TO AVOID
Avoid heat, sparks and open flame. Avoid static discharge
· INCOMPATIBILITY
Strong oxidizers Alkaline materials; Acids;
Chlorine; Concentrated oxygen; Halogens and halogenated compounds; Hydrogen peroxide;
· HAZARDOUS DECOMPOSITION PRODUCTS
Combustion may produce carbon monoxide,
carbon dioxide and other asphyxiants.
· HAZARDOUS POLYMERIZATION
Will not polymerize.
11. ECOLOGICAL INFORMATION
Gasoline spills are toxic to fish and
aquatic flora.
12. DISPOSAL CONSIDERATIONS
Follow federal, state and local
regulations. This material is a RCRA
hazardous waste. Do not flush material
to drain or storm sewer. Contract to
authorized disposal service.
13. TRANSPORT INFORMATION
Governing Body
|
Mode
|
Proper Shipping Name
|
|
DOT |
Ground |
Gasohol |
Governing Body
|
Mode
|
Hazard Class
|
UN/NA No.
|
Label
|
|
DOT |
Ground |
3 (Flammable liquid) |
NA1203 |
|
14. REGULATORY INFORMATION
This product contains the following EPCRA section 313 chemicals subject to the reporting requirements of the Emergency Planning and Community Right-To-Know Act of 1986 (40 CFR 372): Maximum Wt%: Toulene- CAS Number 108-88-3, 41%; Xylene- CAS Number 1330-20-7. 1.7%; Ethyl benzene- CAS Number 100-41-4, 0.2%; N-Hexane- CAS Number 110-54-3, 4.5%; Naphthalene- CAS Number 91-20-3, 0.2%; Benzene- CAS Number 71-43-2, 0.2%. The remaining Sara 313 components listed in Section 14 of the MSDS are less than the reported de minimis levels. This information must be included in all MSDSs that are copied and distributed for this material.
Regulatory List
|
Component
|
CAS No.
|
|
ACGIH - Occupational Exposure Limits - Carcinogens |
BENZENE |
71-43-2 |
|
ACGIH - Occupational Exposure Limits - Carcinogens |
ETHYL ALCOHOL |
64-17-5 |
|
ACGIH - Occupational Exposure Limits - Carcinogens |
ETHYL BENZENE |
100-41-4 |
|
ACGIH - Occupational Exposure Limits - Carcinogens |
NAPHTHALENE |
91-20-3 |
|
ACGIH - Occupational Exposure Limits - Carcinogens |
TOLUENE |
108-88-3 |
|
ACGIH - Occupational Exposure Limits - Carcinogens |
XYLENE |
1330-20-7 |
|
ACGIH - Occupational Exposure Limits - TWAs |
BENZENE |
71-43-2 |
|
ACGIH - Occupational Exposure Limits - TWAs |
CYCLOHEXANE |
110-82-7 |
|
ACGIH - Occupational Exposure Limits - TWAs |
ETHYL ALCOHOL |
64-17-5 |
|
ACGIH - Occupational Exposure Limits - TWAs |
ETHYL BENZENE |
100-41-4 |
|
ACGIH - Occupational Exposure Limits - TWAs |
N-BUTANE |
106-97-8 |
|
ACGIH - Occupational Exposure Limits - TWAs |
N-HEXANE |
110-54-3 |
|
ACGIH - Occupational Exposure Limits - TWAs |
NAPHTHALENE |
91-20-3 |
|
ACGIH - Occupational Exposure Limits - TWAs |
TOLUENE |
108-88-3 |
|
ACGIH - Occupational Exposure Limits - TWAs |
XYLENE |
1330-20-7 |
|
ACGIH - Short Term Exposure Limits |
BENZENE |
71-43-2 |
|
ACGIH - Short Term Exposure Limits |
ETHYL BENZENE |
100-41-4 |
|
ACGIH - Short Term Exposure Limits |
NAPHTHALENE |
91-20-3 |
|
ACGIH - Short Term Exposure Limits |
XYLENE |
1330-20-7 |
|
ACGIH - Skin Absorption Designation |
BENZENE |
71-43-2 |
|
ACGIH - Skin Absorption Designation |
N-HEXANE |
110-54-3 |
|
ACGIH - Skin Absorption Designation |
NAPHTHALENE |
91-20-3 |
|
ACGIH - Skin Absorption Designation |
TOLUENE |
108-88-3 |
|
CAA (Clean Air Act) - High Risk Haz Air Pollutants |
BENZENE |
71-43-2 |
|
CAA (Clean Air Act) - HON Rule - Organic HAPs |
BENZENE |
71-43-2 |
|
CAA (Clean Air Act) - HON Rule - Organic HAPs |
ETHYL BENZENE |
100-41-4 |
|
CAA (Clean Air Act) - HON Rule - Organic HAPs |
N-HEXANE |
110-54-3 |
|
CAA (Clean Air Act) - HON Rule - Organic HAPs |
NAPHTHALENE |
91-20-3 |
|
CAA (Clean Air Act) - HON Rule - Organic HAPs |
TOLUENE |
108-88-3 |
|
CAA (Clean Air Act) - HON Rule - Organic HAPs |
XYLENE |
1330-20-7 |
|
CAA (Clean Air Act) - HON Rule - SOCMI Chemicals |
BENZENE |
71-43-2 |
|
CAA (Clean Air Act) - HON Rule - SOCMI Chemicals |
CYCLOHEXANE |
110-82-7 |
|
CAA (Clean Air Act) - HON Rule - SOCMI Chemicals |
ETHYL BENZENE |
100-41-4 |
|
CAA (Clean Air Act) - HON Rule - SOCMI Chemicals |
N-HEXANE |
110-54-3 |
|
CAA (Clean Air Act) - HON Rule - SOCMI Chemicals |
NAPHTHALENE |
91-20-3 |
|
CAA (Clean Air Act) - HON Rule - SOCMI Chemicals |
TOLUENE |
108-88-3 |
|
CAA (Clean Air Act) - HON Rule - SOCMI Chemicals |
XYLENE |
1330-20-7 |
|
CAA (Clean Air Act) - VOCs in SOCMI |
BENZENE |
71-43-2 |
|
CAA (Clean Air Act) - VOCs in SOCMI |
CYCLOHEXANE |
110-82-7 |
|
CAA (Clean Air Act) - VOCs in SOCMI |
ETHYL ALCOHOL |
64-17-5 |
|
CAA (Clean Air Act) - VOCs in SOCMI |
ETHYL BENZENE |
100-41-4 |
|
CAA (Clean Air Act) - VOCs in SOCMI |
TOLUENE |
108-88-3 |
|
CAA (Clean Air Act) - VOCs in SOCMI |
XYLENE |
1330-20-7 |
|
CAA - 1990 Hazardous Air Pollutants |
BENZENE |
71-43-2 |
|
CAA - 1990 Hazardous Air Pollutants |
ETHYL BENZENE |
100-41-4 |
|
CAA - 1990 Hazardous Air Pollutants |
N-HEXANE |
110-54-3 |
|
CAA - 1990 Hazardous Air Pollutants |
NAPHTHALENE |
91-20-3 |
|
CAA - 1990 Hazardous Air Pollutants |
TOLUENE |
108-88-3 |
|
CAA - 1990 Hazardous Air Pollutants |
XYLENE |
1330-20-7 |
|
California - Prop. 65 - Developmental Toxicity |
BENZENE |
71-43-2 |
|
California - Prop. 65 - Developmental Toxicity |
ETHYL ALCOHOL |
64-17-5 |
|
California - Prop. 65 - Developmental Toxicity |
TOLUENE |
108-88-3 |
|
California - Prop. 65 - Reproductive - Male |
BENZENE |
71-43-2 |
|
California - Proposition 65 - Carcinogens List |
BENZENE |
71-43-2 |
|
California - Proposition 65 - Carcinogens List |
ETHYL BENZENE |
100-41-4 |
|
California - Proposition 65 - Carcinogens List |
NAPHTHALENE |
91-20-3 |
|
Canada - CEPA - Sch. I - List of Toxic Substances |
BENZENE |
71-43-2 |
|
Canada - WHMIS - Ingredient Disclosure |
1,2,4-TRIMETHYLBENZENE |
95-63-6 |
|
Canada - WHMIS - Ingredient Disclosure |
BENZENE |
71-43-2 |
|
Canada - WHMIS - Ingredient Disclosure |
CYCLOHEXANE |
110-82-7 |
|
Canada - WHMIS - Ingredient Disclosure |
ETHYL ALCOHOL |
64-17-5 |
|
Canada - WHMIS - Ingredient Disclosure |
ETHYL BENZENE |
100-41-4 |
|
Canada - WHMIS - Ingredient Disclosure |
N-BUTANE |
106-97-8 |
|
Canada - WHMIS - Ingredient Disclosure |
N-HEXANE |
110-54-3 |
|
Canada - WHMIS - Ingredient Disclosure |
NAPHTHALENE |
91-20-3 |
|
Canada - WHMIS - Ingredient Disclosure |
TOLUENE |
108-88-3 |
|
CERCLA/SARA - Haz Substances and their RQs |
BENZENE |
71-43-2 |
|
CERCLA/SARA - Haz Substances and their RQs |
CYCLOHEXANE |
110-82-7 |
|
CERCLA/SARA - Haz Substances and their RQs |
ETHYL BENZENE |
100-41-4 |
|
CERCLA/SARA - Haz Substances and their RQs |
N-HEXANE |
110-54-3 |
|
CERCLA/SARA - Haz Substances and their RQs |
NAPHTHALENE |
91-20-3 |
|
CERCLA/SARA - Haz Substances and their RQs |
TOLUENE |
108-88-3 |
|
CERCLA/SARA - Haz Substances and their RQs |
XYLENE |
1330-20-7 |
|
CERCLA/SARA - Section 313 - Emission Reporting |
1,2,4-TRIMETHYLBENZENE |
95-63-6 |
|
CERCLA/SARA - Section 313 - Emission Reporting |
BENZENE |
71-43-2 |
|
CERCLA/SARA - Section 313 - Emission Reporting |
CYCLOHEXANE |
110-82-7 |
|
CERCLA/SARA - Section 313 - Emission Reporting |
ETHYL BENZENE |
100-41-4 |
|
CERCLA/SARA - Section 313 - Emission Reporting |
N-HEXANE |
110-54-3 |
|
CERCLA/SARA - Section 313 - Emission Reporting |
NAPHTHALENE |
91-20-3 |
|
CERCLA/SARA - Section 313 - Emission Reporting |
TOLUENE |
108-88-3 |
|
CERCLA/SARA - Section 313 - Emission Reporting |
XYLENE |
1330-20-7 |
|
CWA (Clean Water Act) - Hazardous Substances |
BENZENE |
71-43-2 |
|
CWA (Clean Water Act) - Hazardous Substances |
CYCLOHEXANE |
110-82-7 |
|
CWA (Clean Water Act) - Hazardous Substances |
ETHYL BENZENE |
100-41-4 |
|
CWA (Clean Water Act) - Hazardous Substances |
NAPHTHALENE |
91-20-3 |
|
CWA (Clean Water Act) - Hazardous Substances |
TOLUENE |
108-88-3 |
|
CWA (Clean Water Act) - Hazardous Substances |
XYLENE |
1330-20-7 |
|
CWA (Clean Water Act) - Priority Pollutants |
BENZENE |
71-43-2 |
|
CWA (Clean Water Act) - Priority Pollutants |
ETHYL BENZENE |
100-41-4 |
|
CWA (Clean Water Act) - Priority Pollutants |
NAPHTHALENE |
91-20-3 |
|
CWA (Clean Water Act) - Priority Pollutants |
TOLUENE |
108-88-3 |
|
CWA (Clean Water Act) - Toxic Pollutants |
BENZENE |
71-43-2 |
|
CWA (Clean Water Act) - Toxic Pollutants |
ETHYL BENZENE |
100-41-4 |
|
CWA (Clean Water Act) - Toxic Pollutants |
NAPHTHALENE |
91-20-3 |
|
CWA (Clean Water Act) - Toxic Pollutants |
TOLUENE |
108-88-3 |
|
DEA - List II Essential Chemicals |
TOLUENE |
108-88-3 |
|
IARC - Group 1 (carcinogenic to humans) |
BENZENE |
71-43-2 |
|
IARC - Group 2B (Possibly carcinogenic to humans) |
ETHYL BENZENE |
100-41-4 |
|
IARC - Group 2B (Possibly carcinogenic to humans) |
NAPHTHALENE |
91-20-3 |
|
IARC - Group 3 (not classifiable) |
TOLUENE |
108-88-3 |
|
IARC - Group 3 (not classifiable) |
XYLENE |
1330-20-7 |
|
Inventory - Australia (AICS) |
1,2,4-TRIMETHYLBENZENE |
95-63-6 |
|
Inventory - Australia (AICS) |
ALKYLATE |
64741-66-8 |
|
Inventory - Australia (AICS) |
BENZENE |
71-43-2 |
|
Inventory - Australia (AICS) |
CYCLOHEXANE |
110-82-7 |
|
Inventory - Australia (AICS) |
ETHYL ALCOHOL |
64-17-5 |
|
Inventory - Australia (AICS) |
ETHYL BENZENE |
100-41-4 |
|
Inventory - Australia (AICS) |
N-BUTANE |
106-97-8 |
|
Inventory - Australia (AICS) |
N-HEXANE |
110-54-3 |
|
Inventory - Australia (AICS) |
NAPHTHALENE |
91-20-3 |
|
Inventory - Australia (AICS) |
TOLUENE |
108-88-3 |
|
Inventory - Australia (AICS) |
XYLENE |
1330-20-7 |
|
Inventory - Canada - Domestic Substances List |
1,2,4-TRIMETHYLBENZENE |
95-63-6 |
|
Inventory - Canada - Domestic Substances List |
ALKYLATE |
64741-66-8 |
|
Inventory - Canada - Domestic Substances List |
BENZENE |
71-43-2 |
|
Inventory - Canada - Domestic Substances List |
CYCLOHEXANE |
110-82-7 |
|
Inventory - Canada - Domestic Substances List |
ETHYL ALCOHOL |
64-17-5 |
|
Inventory - Canada - Domestic Substances List |
ETHYL BENZENE |
100-41-4 |
|
Inventory - Canada - Domestic Substances List |
N-BUTANE |
106-97-8 |
|
Inventory - Canada - Domestic Substances List |
N-HEXANE |
110-54-3 |
|
Inventory - Canada - Domestic Substances List |
NAPHTHALENE |
91-20-3 |
|
Inventory - Canada - Domestic Substances List |
TOLUENE |
108-88-3 |
|
Inventory - Canada - Domestic Substances List |
XYLENE |
1330-20-7 |
|
Inventory - China |
1,2,4-TRIMETHYLBENZENE |
95-63-6 |
|
Inventory - China |
ALKYLATE |
64741-66-8 |
|
Inventory - China |
BENZENE |
71-43-2 |
|
Inventory - China |
CYCLOHEXANE |
110-82-7 |
|
Inventory - China |
ETHYL ALCOHOL |
64-17-5 |
|
Inventory - China |
ETHYL BENZENE |
100-41-4 |
|
Inventory - China |
N-BUTANE |
106-97-8 |
|
Inventory - China |
N-HEXANE |
110-54-3 |
|
Inventory - China |
NAPHTHALENE |
91-20-3 |
|
Inventory - China |
TOLUENE |
108-88-3 |
|
Inventory - China |
XYLENE |
1330-20-7 |
|
Inventory - European EINECS Inventory |
1,2,4-TRIMETHYLBENZENE |
95-63-6 |
|
Inventory - European EINECS Inventory |
ALKYLATE |
64741-66-8 |
|
Inventory - European EINECS Inventory |
BENZENE |
71-43-2 |
|
Inventory - European EINECS Inventory |
CYCLOHEXANE |
110-82-7 |
|
Inventory - European EINECS Inventory |
ETHYL ALCOHOL |
64-17-5 |
|
Inventory - European EINECS Inventory |
ETHYL BENZENE |
100-41-4 |
|
Inventory - European EINECS Inventory |
N-BUTANE |
106-97-8 |
|
Inventory - European EINECS Inventory |
N-HEXANE |
110-54-3 |
|
Inventory - European EINECS Inventory |
NAPHTHALENE |
91-20-3 |
|
Inventory - European EINECS Inventory |
TOLUENE |
108-88-3 |
|
Inventory - European EINECS Inventory |
XYLENE |
1330-20-7 |
|
Inventory - Japan - (ENCS) |
1,2,4-TRIMETHYLBENZENE |
95-63-6 |
|
Inventory - Japan - (ENCS) |
BENZENE |
71-43-2 |
|
Inventory - Japan - (ENCS) |
CYCLOHEXANE |
110-82-7 |
|
Inventory - Japan - (ENCS) |
ETHYL ALCOHOL |
64-17-5 |
|
Inventory - Japan - (ENCS) |
ETHYL BENZENE |
100-41-4 |
|
Inventory - Japan - (ENCS) |
N-BUTANE |
106-97-8 |
|
Inventory - Japan - (ENCS) |
N-HEXANE |
110-54-3 |
|
Inventory - Japan - (ENCS) |
NAPHTHALENE |
91-20-3 |
|
Inventory - Japan - (ENCS) |
TOLUENE |
108-88-3 |
|
Inventory - Japan - (ENCS) |
XYLENE |
1330-20-7 |
|
Inventory - Korea - Existing and Evaluated |
1,2,4-TRIMETHYLBENZENE |
95-63-6 |
|
Inventory - Korea - Existing and Evaluated |
ALKYLATE |
64741-66-8 |
|
Inventory - Korea - Existing and Evaluated |
BENZENE |
71-43-2 |
|
Inventory - Korea - Existing and Evaluated |
CYCLOHEXANE |
110-82-7 |
|
Inventory - Korea - Existing and Evaluated |
ETHYL ALCOHOL |
64-17-5 |
|
Inventory - Korea - Existing and Evaluated |
ETHYL BENZENE |
100-41-4 |
|
Inventory - Korea - Existing and Evaluated |
N-BUTANE |
106-97-8 |
|
Inventory - Korea - Existing and Evaluated |
N-HEXANE |
110-54-3 |
|
Inventory - Korea - Existing and Evaluated |
NAPHTHALENE |
91-20-3 |
|
Inventory - Korea - Existing and Evaluated |
TOLUENE |
108-88-3 |
|
Inventory - Korea - Existing and Evaluated |
XYLENE |
1330-20-7 |
|
Inventory - New Zealand |
1,2,4-TRIMETHYLBENZENE |
95-63-6 |
|
Inventory - New Zealand |
ALKYLATE |
64741-66-8 |
|
Inventory - New Zealand |
BENZENE |
71-43-2 |
|
Inventory - New Zealand |
CYCLOHEXANE |
110-82-7 |
|
Inventory - New Zealand |
ETHYL ALCOHOL |
64-17-5 |
|
Inventory - New Zealand |
ETHYL BENZENE |
100-41-4 |
|
Inventory - New Zealand |
N-BUTANE |
106-97-8 |
|
Inventory - New Zealand |
N-HEXANE |
110-54-3 |
|
Inventory - New Zealand |
NAPHTHALENE |
91-20-3 |
|
Inventory - New Zealand |
TOLUENE |
108-88-3 |
|
Inventory - New Zealand |
XYLENE |
1330-20-7 |
|
Inventory - Philippines Inventory (PICCS) |
1,2,4-TRIMETHYLBENZENE |
95-63-6 |
|
Inventory - Philippines Inventory (PICCS) |
ALKYLATE |
64741-66-8 |
|
Inventory - Philippines Inventory (PICCS) |
BENZENE |
71-43-2 |
|
Inventory - Philippines Inventory (PICCS) |
CYCLOHEXANE |
110-82-7 |
|
Inventory - Philippines Inventory (PICCS) |
ETHYL ALCOHOL |
64-17-5 |
|
Inventory - Philippines Inventory (PICCS) |
ETHYL BENZENE |
100-41-4 |
|
Inventory - Philippines Inventory (PICCS) |
N-BUTANE |
106-97-8 |
|
Inventory - Philippines Inventory (PICCS) |
N-HEXANE |
110-54-3 |
|
Inventory - Philippines Inventory (PICCS) |
NAPHTHALENE |
91-20-3 |
|
Inventory - Philippines Inventory (PICCS) |
TOLUENE |
108-88-3 |
|
Inventory - Philippines Inventory (PICCS) |
XYLENE |
1330-20-7 |
|
Inventory - TSCA - Sect. 8(b) Inventory |
1,2,4-TRIMETHYLBENZENE |
95-63-6 |
|
Inventory - TSCA - Sect. 8(b) Inventory |
ALKYLATE |
64741-66-8 |
|
Inventory - TSCA - Sect. 8(b) Inventory |
BENZENE |
71-43-2 |
|
Inventory - TSCA - Sect. 8(b) Inventory |
CYCLOHEXANE |
110-82-7 |
|
Inventory - TSCA - Sect. 8(b) Inventory |
ETHYL ALCOHOL |
64-17-5 |
|
Inventory - TSCA - Sect. 8(b) Inventory |
ETHYL BENZENE |
100-41-4 |
|
Inventory - TSCA - Sect. 8(b) Inventory |
N-BUTANE |
106-97-8 |
|
Inventory - TSCA - Sect. 8(b) Inventory |
N-HEXANE |
110-54-3 |
|
Inventory - TSCA - Sect. 8(b) Inventory |
NAPHTHALENE |
91-20-3 |
|
Inventory - TSCA - Sect. 8(b) Inventory |
TOLUENE |
108-88-3 |
|
Inventory - TSCA - Sect. 8(b) Inventory |
XYLENE |
1330-20-7 |
|
Massachusetts - Right To Know List |
1,2,4-TRIMETHYLBENZENE |
95-63-6 |
|
Massachusetts - Right To Know List |
BENZENE |
71-43-2 |
|
Massachusetts - Right To Know List |
CYCLOHEXANE |
110-82-7 |
|
Massachusetts - Right To Know List |
ETHYL ALCOHOL |
64-17-5 |
|
Massachusetts - Right To Know List |
ETHYL BENZENE |
100-41-4 |
|
Massachusetts - Right To Know List |
N-BUTANE |
106-97-8 |
|
Massachusetts - Right To Know List |
N-HEXANE |
110-54-3 |
|
Massachusetts - Right To Know List |
NAPHTHALENE |
91-20-3 |
|
Massachusetts - Right To Know List |
TOLUENE |
108-88-3 |
|
Massachusetts - Right To Know List |
XYLENE |
1330-20-7 |
|
New Jersey - Department of Health RTK List |
1,2,4-TRIMETHYLBENZENE |
95-63-6 |
|
New Jersey - Department of Health RTK List |
BENZENE |
71-43-2 |
|
New Jersey - Department of Health RTK List |
CYCLOHEXANE |
110-82-7 |
|
New Jersey - Department of Health RTK List |
ETHYL ALCOHOL |
64-17-5 |
|
New Jersey - Department of Health RTK List |
ETHYL BENZENE |
100-41-4 |
|
New Jersey - Department of Health RTK List |
N-BUTANE |
106-97-8 |
|
New Jersey - Department of Health RTK List |
N-HEXANE |
110-54-3 |
|
New Jersey - Department of Health RTK List |
NAPHTHALENE |
91-20-3 |
|
New Jersey - Department of Health RTK List |
TOLUENE |
108-88-3 |
|
New Jersey - Department of Health RTK List |
XYLENE |
1330-20-7 |
|
New Jersey - Env Hazardous Substances List |
1,2,4-TRIMETHYLBENZENE |
95-63-6 |
|
New Jersey - Env Hazardous Substances List |
BENZENE |
71-43-2 |
|
New Jersey - Env Hazardous Substances List |
CYCLOHEXANE |
110-82-7 |
|
New Jersey - Env Hazardous Substances List |
ETHYL BENZENE |
100-41-4 |
|
New Jersey - Env Hazardous Substances List |
N-BUTANE |
106-97-8 |
|
New Jersey - Env Hazardous Substances List |
N-HEXANE |
110-54-3 |
|
New Jersey - Env Hazardous Substances List |
NAPHTHALENE |
91-20-3 |
|
New Jersey - Env Hazardous Substances List |
TOLUENE |
108-88-3 |
|
New Jersey - Env Hazardous Substances List |
XYLENE |
1330-20-7 |
|
New Jersey - Special Hazardous Substances |
BENZENE |
71-43-2 |
|
New Jersey - Special Hazardous Substances |
CYCLOHEXANE |
110-82-7 |
|
New Jersey - Special Hazardous Substances |
ETHYL ALCOHOL |
64-17-5 |
|
New Jersey - Special Hazardous Substances |
ETHYL BENZENE |
100-41-4 |
|
New Jersey - Special Hazardous Substances |
N-BUTANE |
106-97-8 |
|
New Jersey - Special Hazardous Substances |
N-HEXANE |
110-54-3 |
|
New Jersey - Special Hazardous Substances |
TOLUENE |
108-88-3 |
|
New Jersey - Special Hazardous Substances |
XYLENE |
1330-20-7 |
|
NTP - Report on Carcinogens - Known Carcinogens |
BENZENE |
71-43-2
|
|
NTP - Report on Carcinogens - Suspect Carcinogens |
NAPHTHALENE |
91-20-3 |
|
OSHA - Final PELs - Ceiling Limits |
BENZENE |
71-43-2 |
|
OSHA - Final PELs - Ceiling Limits |
TOLUENE |
108-88-3 |
|
OSHA - Final PELs - Short Term Exposure Limits |
BENZENE |
71-43-2 |
|
OSHA - Final PELs - Time Weighted Averages |
BENZENE |
71-43-2 |
|
OSHA - Final PELs - Time Weighted Averages |
CYCLOHEXANE |
110-82-7 |
|
OSHA - Final PELs - Time Weighted Averages |
ETHYL ALCOHOL |
64-17-5 |
|
OSHA - Final PELs - Time Weighted Averages |
ETHYL BENZENE |
100-41-4 |
|
OSHA - Final PELs - Time Weighted Averages |
N-HEXANE |
110-54-3 |
|
OSHA - Final PELs - Time Weighted Averages |
NAPHTHALENE |
91-20-3 |
|
OSHA - Final PELs - Time Weighted Averages |
TOLUENE |
108-88-3 |
|
OSHA - Final PELs - Time Weighted Averages |
XYLENE |
1330-20-7 |
|
OSHA - Hazard Communication Carcinogens |
BENZENE |
71-43-2 |
|
OSHA - Specifically Regulated Carcinogens |
BENZENE |
71-43-2 |
|
Pennsylvania - RTK (Right to Know) List |
1,2,4-TRIMETHYLBENZENE |
95-63-6 |
|
Pennsylvania - RTK (Right to Know) List |
BENZENE |
71-43-2 |
|
Pennsylvania - RTK (Right to Know) List |
CYCLOHEXANE |
110-82-7 |
|
Pennsylvania - RTK (Right to Know) List |
ETHYL ALCOHOL |
64-17-5 |
|
Pennsylvania - RTK (Right to Know) List |
ETHYL BENZENE |
100-41-4 |
|
Pennsylvania - RTK (Right to Know) List |
N-BUTANE |
106-97-8 |
|
Pennsylvania - RTK (Right to Know) List |
N-HEXANE |
110-54-3 |
|
Pennsylvania - RTK (Right to Know) List |
NAPHTHALENE |
91-20-3 |
|
Pennsylvania - RTK (Right to Know) List |
TOLUENE |
108-88-3 |
|
Pennsylvania - RTK (Right to Know) List |
XYLENE |
1330-20-7 |
|
Pennsylvania - RTK - Environmental Hazard List |
1,2,4-TRIMETHYLBENZENE |
95-63-6 |
|
Pennsylvania - RTK - Environmental Hazard List |
BENZENE |
71-43-2 |
|
Pennsylvania - RTK - Environmental Hazard List |
CYCLOHEXANE |
110-82-7 |
|
Pennsylvania - RTK - Environmental Hazard List |
ETHYL BENZENE |
100-41-4 |
|
Pennsylvania - RTK - Environmental Hazard List |
NAPHTHALENE |
91-20-3 |
|
Pennsylvania - RTK - Environmental Hazard List |
TOLUENE |
108-88-3 |
|
Pennsylvania - RTK - Environmental Hazard List |
XYLENE |
1330-20-7 |
|
Pennsylvania - RTK - Special Hazardous Substances |
BENZENE |
71-43-2 |
|
TSCA - Sect. 12(b) - Export Notification |
CYCLOHEXANE |
110-82-7 |
|
TSCA - Sect. 12(b) - Export Notification |
N-HEXANE |
110-54-3 |
|
TSCA - Sect. 12(b) - Export Notification |
NAPHTHALENE |
91-20-3 |
|
TSCA - Section 4 - Chemical Test Rules |
CYCLOHEXANE |
110-82-7 |
|
TSCA - Section 4 - Chemical Test Rules |
NAPHTHALENE |
91-20-3 |
|
U.S. - DOT - Hazardous Substances and RQs (App A) |
BENZENE |
71-43-2 |
|
U.S. - DOT - Hazardous Substances and RQs (App A) |
CYCLOHEXANE |
110-82-7 |
|
U.S. - DOT - Hazardous Substances and RQs (App A) |
ETHYL BENZENE |
100-41-4 |
|
U.S. - DOT - Hazardous Substances and RQs (App A) |
N-HEXANE |
110-54-3 |
|
U.S. - DOT - Hazardous Substances and RQs (App A) |
NAPHTHALENE |
91-20-3 |
|
U.S. - DOT - Hazardous Substances and RQs (App A) |
TOLUENE |
108-88-3 |
|
U.S. - DOT - Hazardous Substances and RQs (App A) |
XYLENE |
1330-20-7 |
Title III Classifications Sections
311,312:
·
Acute: YES
·
Chronic: YES
·
Fire: YES
· Reactivity: NO
· Sudden Release of Pressure: NO
15. OTHER INFORMATION
Follow all MSDS/label precautions even
after container is emptied because it may retain product residue. Keep out of reach of children. Precautionary labeling for pumps, portable
containers, and drums is required. A "hazardous when empty" pictogram
and D.O.T. flammable liquid label are also required for drums. Details
available upon request. Because benzene is present in this product above 0.1%,
the Osha Standard for benzene is applicable to work locations upstream of final
discharge from terminals. Consult 29CFR1910.1028 for details. Prolonged and
repeated excessive exposures to benzene can result in blood disorders ranging
from anemia to leukemia. Sun recommends that exposures to benzene be kept below
0.5 ppm for 8-hours; 2.5 ppm for 15-min. Normal service station operations are
below these values. For use as motor fuel only. Do not use for any other
purpose. NOTE TO PHYSICIAN: Catecholamines and similar adrenergic drugs
are generally contraindicated because of potential for increased sensitivity of
the heart from hydrocarbon overexposure and subsequent ventricular
fibrillation. EKG monitoring may be
indicated and bronchodilators should be selected with care. Following injection, prompt debridement of
the wound is necessary to minimize necrosis and tissue loss. COMPONENT TOXICITY: Overexposure to naphthalene, a minor
component of this product, may cause skin, eye and respiratory tract
irritation, anemia, loss of vision, nervous system effects and kidney and
thymus damage. Also, exposure to
naphthalene has produced "respiratory tract" tumors in laboratory
animals.. Ethylbenzene, a component of
this product, has been designated by the International Agency for Research on
Cancer as "possibly carcinogenic to humans", based on increased tumor
incidence in laboratory animals.
Overexposure may lead to nervous system effects, including drowsiness,
dizziness, nausea, headaches, paralysis, loss of consciousness and even
death. Repeated overexposure has caused
a hearing loss in laboratory animals.
Hours of exposure to high airborne concentrations of xylene, a minor
component of this product, has caused a hearing loss in laboratory animals.